%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% % % Two line-disjoint paths (path #1 and path #2) for the derivation of the lowest ortho energy of H2O-18 % %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% % % Notes: % % (a) E0 : lowest ortho energy value (with associated uncertainty) in cm-1 % [see Supplementary Equations 1-2 in the Supplementary Information % of Nat. Commun. 11, 1708. (2020)] % (b) wave_nb : transition wavenumber in cm-1 % (c) unc : wavenumber uncertainty in cm-1 % (d) upper assignment (six columns) : rovibrational label (v_1, v_2, v_3, J, K_a, and K_c) % of the upper energy level % (e) lower assignment (six columns) : rovibrational label (v_1, v_2, v_3, J, K_a, and K_c) % of the lower energy level % (f) line tag : line identifier standing for % 06GoMaGuKn ~ J. Mol. Spectrosc. 240, 191-194 (2006), % 21DiToSiCo ~ this study (NICE-OHMS experiments), and % ops ~ 0/1 splitting (virtual transition, see table_S7.txt) % (g) sign : sign of the transition wavenumber within the path % [see Supplementary Equations 1-2 in the Supplementary Information of % of Nat. Commun. 11, 1708. (2020)] % %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% path #1: E0[cm-1] = 23.75490369 +- 0.00000108 wave_nb/cm-1 unc/cm-1 upper assignment lower assignment line tag sign 7220.7481721105 6.004e-08 2 0 0 1 1 1 0 0 0 0 0 0 21DiToSiCo.118 1 7150.8207473318 6.671e-08 2 0 0 1 1 1 0 0 0 2 0 2 21DiToSiCo.92 -1 7251.9673878087 7.005e-08 2 0 0 3 1 3 0 0 0 2 0 2 21DiToSiCo.137 1 7007.4353889416 6.338e-08 2 0 0 3 1 3 0 0 0 4 2 2 21DiToSiCo.7 -1 10.7562783317 6.671e-08 0 0 0 5 1 5 0 0 0 4 2 2 06GoMaGuKn.3 1 7289.0130064746 6.338e-08 2 0 0 6 0 6 0 0 0 5 1 5 21DiToSiCo.162 1 7073.0486107759 6.671e-08 2 0 0 6 0 6 0 0 0 6 1 5 21DiToSiCo.45 -1 7291.8927563114 6.671e-08 0 2 1 6 5 2 0 0 0 6 1 5 21DiToSiCo.166 1 7020.3112399512 6.338e-08 0 2 1 6 5 2 0 0 0 7 3 5 21DiToSiCo.17 -1 7258.7661664824 6.338e-08 2 0 0 7 4 4 0 0 0 7 3 5 21DiToSiCo.142 1 7020.5376461305 8.339e-08 2 0 0 7 4 4 0 0 0 7 5 3 21DiToSiCo.18 -1 7283.0399140461 6.671e-08 2 0 0 7 6 2 0 0 0 7 5 3 21DiToSiCo.157 1 7086.8241109921 1.334e-07 2 0 0 7 6 2 0 0 0 8 5 3 21DiToSiCo.57 -1 7277.0855956290 8.006e-08 2 0 0 8 6 2 0 0 0 8 5 3 21DiToSiCo.153 1 7058.2734569794 7.338e-08 2 0 0 8 6 2 0 0 0 9 5 5 21DiToSiCo.37 -1 7271.6815550477 1.034e-07 2 0 0 9 6 4 0 0 0 9 5 5 21DiToSiCo.149 1 7163.0214208391 2.502e-07 2 0 0 9 6 4 0 0 0 8 7 1 21DiToSiCo.98 -1 7221.1187632245 3.002e-07 1 2 0 8 8 0 0 0 0 8 7 1 21DiToSiCo.119 1 0.0000046332 1.401e-07 1 2 0 8 8 0 1 2 0 8 8 1 ops.1 -1 7221.1195314060 2.235e-07 1 2 0 8 8 1 0 0 0 8 7 2 21DiToSiCo.120 -1 7153.1810126624 8.606e-07 0 0 2 9 4 5 0 0 0 8 7 2 21DiToSiCo.93 1 7259.2465533139 7.338e-08 0 0 2 9 4 5 0 0 0 9 5 4 21DiToSiCo.143 -1 7055.4575120132 7.338e-08 2 0 0 8 6 3 0 0 0 9 5 4 21DiToSiCo.36 1 7277.7009832215 6.338e-08 2 0 0 8 6 3 0 0 0 8 5 4 21DiToSiCo.155 -1 7087.6912120685 8.339e-08 2 0 0 7 6 1 0 0 0 8 5 4 21DiToSiCo.59 1 7282.8566027735 6.671e-08 2 0 0 7 6 1 0 0 0 7 5 2 21DiToSiCo.156 -1 7079.4783835890 8.339e-08 0 0 2 6 4 3 0 0 0 7 5 2 21DiToSiCo.50 1 7250.6052546292 6.004e-08 0 0 2 6 4 3 0 0 0 6 5 2 21DiToSiCo.136 -1 7106.8868201281 6.004e-08 0 0 2 5 4 1 0 0 0 6 5 2 21DiToSiCo.69 1 7341.5804513401 6.338e-08 0 0 2 5 4 1 0 0 0 6 3 4 21DiToSiCo.192 -1 7087.1707016625 6.338e-08 0 0 2 5 0 5 0 0 0 6 3 4 21DiToSiCo.58 1 7287.2070551955 7.005e-08 0 0 2 5 0 5 0 0 0 6 1 6 21DiToSiCo.161 -1 7098.0814000097 9.673e-08 0 2 1 6 3 3 0 0 0 6 1 6 21DiToSiCo.62 1 7037.6988501926 6.338e-08 0 2 1 6 3 3 0 0 0 5 3 2 21DiToSiCo.28 -1 7198.7157662018 6.671e-08 0 0 2 4 2 3 0 0 0 5 3 2 21DiToSiCo.107 1 7306.0840182477 7.338e-08 0 0 2 4 2 3 0 0 0 5 1 4 21DiToSiCo.176 -1 7073.6118659830 7.672e-08 2 0 0 4 2 3 0 0 0 5 1 4 21DiToSiCo.46 1 7248.1438453031 6.338e-08 2 0 0 4 2 3 0 0 0 4 1 4 21DiToSiCo.134 -1 13.0292729379 1.334e-07 0 0 0 4 1 4 0 0 0 3 2 1 06GoMaGuKn.4 -1 7144.9745078344 5.671e-08 1 0 1 2 2 0 0 0 0 3 2 1 21DiToSiCo.89 1 7332.0188287959 6.671e-08 1 0 1 2 2 0 0 0 0 1 0 1 21DiToSiCo.187 -1 path #2: E0[cm-1] = 23.75490369 +- 0.00000136 wave_nb/cm-1 unc/cm-1 upper assignment lower assignment line tag sign 7252.0206484848 5.671e-08 1 0 1 1 0 1 0 0 0 0 0 0 21DiToSiCo.138 1 7182.0932239196 7.338e-08 1 0 1 1 0 1 0 0 0 2 0 2 21DiToSiCo.100 -1 7290.9929180673 6.671e-08 1 0 1 3 0 3 0 0 0 2 0 2 21DiToSiCo.164 1 7139.6863540210 9.006e-08 1 0 1 3 0 3 0 0 0 4 0 4 21DiToSiCo.86 -1 7277.6468144672 6.338e-08 2 0 0 5 1 5 0 0 0 4 0 4 21DiToSiCo.154 1 7054.0346402243 6.338e-08 2 0 0 5 1 5 0 0 0 6 0 6 21DiToSiCo.34 -1 7211.6481939516 7.672e-08 1 0 1 5 2 3 0 0 0 6 0 6 21DiToSiCo.113 1 7051.9502534784 6.671e-08 1 0 1 5 2 3 0 0 0 5 4 2 21DiToSiCo.33 -1 7340.3378584027 8.339e-08 0 0 2 6 1 5 0 0 0 5 4 2 21DiToSiCo.191 1 7022.9862488469 7.005e-08 0 0 2 6 1 5 0 0 0 7 4 4 21DiToSiCo.21 -1 7191.3549086248 6.671e-08 1 0 1 7 4 3 0 0 0 7 4 4 21DiToSiCo.104 1 7080.0562242330 2.035e-07 1 0 1 7 4 3 0 0 0 6 6 0 21DiToSiCo.51 -1 7210.6618716906 7.672e-08 0 0 2 6 5 1 0 0 0 6 6 0 21DiToSiCo.112 1 7039.6870275969 1.001e-07 0 0 2 6 5 1 0 0 0 7 6 2 21DiToSiCo.31 -1 7208.0900645039 8.673e-08 0 0 2 7 5 3 0 0 0 7 6 2 21DiToSiCo.108 1 7012.7961089168 9.673e-08 0 0 2 7 5 3 0 0 0 8 6 2 21DiToSiCo.13 -1 7134.0251170862 2.068e-07 1 0 1 9 4 5 0 0 0 8 6 2 21DiToSiCo.85 1 7100.4595398828 1.901e-07 1 0 1 9 4 5 0 0 0 10 2 8 21DiToSiCo.65 -1 7333.6567535732 6.104e-07 1 0 1 9 6 3 0 0 0 10 2 8 21DiToSiCo.188 1 7147.7894646502 1.801e-07 1 0 1 9 6 3 0 0 0 9 6 4 21DiToSiCo.91 -1 7267.8952538492 8.439e-07 0 0 2 8 7 1 0 0 0 9 6 4 21DiToSiCo.145 1 7117.9901219496 6.671e-08 0 0 2 8 7 1 0 0 0 8 8 0 21DiToSiCo.76 -1 0.0000071116 6.004e-08 0 0 0 8 8 0 0 0 0 8 8 1 ops.2 -1 7330.9434336637 1.634e-07 0 0 2 9 7 2 0 0 0 8 8 1 21DiToSiCo.186 1 7237.2900301781 4.837e-07 0 0 2 9 7 2 0 0 0 10 6 5 21DiToSiCo.128 -1 7039.6705297103 1.634e-07 2 0 0 9 7 2 0 0 0 10 6 5 21DiToSiCo.30 1 7283.0695897393 9.340e-08 2 0 0 9 7 2 0 0 0 9 6 3 21DiToSiCo.158 -1 7044.3917298180 2.568e-07 0 0 2 9 3 6 0 0 0 9 6 3 21DiToSiCo.32 1 7088.9979677107 6.671e-08 0 0 2 9 3 6 0 0 0 10 4 7 21DiToSiCo.60 -1 7022.6447642122 8.673e-08 2 0 0 9 5 4 0 0 0 10 4 7 21DiToSiCo.20 1 7197.6662391520 7.672e-08 2 0 0 9 5 4 0 0 0 8 6 3 21DiToSiCo.106 -1 7013.1906822686 6.671e-08 0 0 2 7 5 2 0 0 0 8 6 3 21DiToSiCo.14 1 7208.4437404526 1.968e-07 0 0 2 7 5 2 0 0 0 7 6 1 21DiToSiCo.109 -1 7039.6149587826 1.134e-07 0 0 2 6 5 2 0 0 0 7 6 1 21DiToSiCo.29 1 7210.5957799245 8.339e-08 0 0 2 6 5 2 0 0 0 6 6 1 21DiToSiCo.111 -1 7075.8694788212 8.673e-08 1 0 1 7 4 4 0 0 0 6 6 1 21DiToSiCo.47 1 7328.6106432004 6.004e-08 1 0 1 7 4 4 0 0 0 7 2 5 21DiToSiCo.184 -1 7244.2544036215 7.005e-08 2 0 0 6 5 2 0 0 0 7 2 5 21DiToSiCo.131 1 7273.6743313503 6.004e-08 2 0 0 6 5 2 0 0 0 6 4 3 21DiToSiCo.151 -1 7063.4803527145 6.671e-08 1 0 1 6 2 4 0 0 0 6 4 3 21DiToSiCo.40 1 7264.0624133446 7.672e-08 1 0 1 6 2 4 0 0 0 6 2 5 21DiToSiCo.144 -1 7119.0630058579 6.338e-08 0 2 1 6 4 2 0 0 0 6 2 5 21DiToSiCo.77 1 7345.4670692816 6.004e-08 0 2 1 6 4 2 0 0 0 5 0 5 21DiToSiCo.195 -1 7077.1519858615 7.005e-08 2 0 0 4 1 4 0 0 0 5 0 5 21DiToSiCo.49 1 7102.5786127615 6.671e-08 2 0 0 4 1 4 0 0 0 4 2 3 21DiToSiCo.67 -1 7054.2508803240 7.338e-08 2 0 0 3 1 2 0 0 0 4 2 3 21DiToSiCo.35 1 7216.5343280651 6.338e-08 2 0 0 3 1 2 0 0 0 3 0 3 21DiToSiCo.114 -1 7125.1845075302 6.338e-08 2 0 0 2 1 2 0 0 0 3 0 3 21DiToSiCo.78 1 7237.7662522084 7.005e-08 2 0 0 2 1 2 0 0 0 1 0 1 21DiToSiCo.129 -1